Frontal Polymerization Bibliography

  1. Chechilo, N. M.; Khvilivitskii, R. J.; Enikolopyan, N. S. "On the Phenomenon of Polymerization Reaction Spreading," Dokl. Akad. Nauk SSSR 1972, 204, 1180-1181.
  2. Butakov, A. A.; Maksimov, E. I. "An experimental study of the heat regimes of tubular reactor,"Doklady Akad. Nauk SSSR 1973, 209, 643.
  3. Begishev, V. P.; Volpert, V. A.; Davtyan, S. P.; Malkin, A. Y. "On some Features of the Process of Anionic Activated Polymerization of e-caprolactams under Conditions of Wave Propagation," Dokl. Akad. Nauk SSSR 1973, 208, 892.
  4. Begishev, V. P.; Volpert, V. A.; Davtyan, S. P.; Malkin, A. Y. "On some Features of the Process of Anionic Activated Polymerization of e-caprolactams under Conditions of Wave Propagation," Dokl. Akad. Nauk SSSR 1973, 208, 892.
  5. Khanukaev, B. B.; Kozhushner, M. A.; Enikolopyan, N. S. "Theory of the Propagation of a Polymerization Front,"Dokl. Phys. Chem. 1974, 214, 84-87.
  6. Khanukaev, B. B.; Kozhushner, M. A.; Enikolopyan, N. S. "Theory of Polymerization-Front Propagation,"Combust. Explos. Shock Waves 1974, 10, 562-568.
  7. Enikolopyan, N. S.; Kozhushner, M. A.; Khanukaev, B. B. "Molecular Weight Distribution during Isothermal and Frontal Polymerization,"Doklady Phys. Chem. 1974, 217, 676-678.
  8. Chechilo, N. M.; Enikolopyan, N. S. "Structure of the Polymerization Wave Front and Propagation Mechanism of the Polymerization Reaction,"Dokl. Phys. Chem. 1974, 214, 174-176.
  9. Chechilo, N. M.; Enikolopyan, N. S. "Effect of the Concentration and Nature of Initiators on the Propagation Process in Polymerization,"Dokl. Phys. Chem. 1975, 221, 392-394.
  10. Aleksanyan, G. G.; Arutyunyan, K. A.; Bodneva, V. L.; Davtyan, S. P.; Prut, E. V.; Rozenberg, B. A.; Shkadinskii, K. G.; Yenikolopyan, N. S. "Some Rules Governing the Extension of the Front of Radical Polymerization of Vinyl Monomers,"Polym. Sci. USSR 1975, A17, 1052-1059.
  11. Chechilo, N. M.; Enikolopyan, N. S. "Effect of Pressure and Initial Temperature of the Reaction Mixture during Propagation of a Polymerization Reaction,"Dokl. Phys. Chem. 1976, 230, 840-843.
  12. Arutiunian, K. A.; Davtyan, S. P.; Rozenberg, B. A.; Enikolopyan, N. S. "Curing of epoxy resins of bis-phenol A by amines under conditions of reaction front propagation," Dokl. Akad. Nauk SSSR 1975, 223, 657-660.
  13. Surkov, N. F.; Davtyan, S. P.; Rozenberg, B. A.; Enikolopyan, N. S. "Calculation of the Steady Velocity of the Reaction Front during Hardening of Epoxy Oligomers by Diamines,"Dokl. Phys. Chem. 1976, 228, 435-438.
  14. Davtyan, S. P.; Gukasova, E. A.; Makarova, S. B.; Enikolopyan, N. S. "Gel Effect During Adiabatic Polymerization of n-Butyl Methacrylate,"Doklady Phys. Chem. 1976, 231, 1279-1281.
  15. Davtyan, S. P.; Surkov, N. F.; Rozenberg, B. A.; Enikolopyan, N. S. "Influence of the Gel Effect on the Kinetics of Radical Polymerization under the Conditions of the Polymerization Front Propagation,"Dokl. Phys. Chem. 1977, 232, 64-67.
  16. Butakov, A. A.; Shtessel, E. A. "The effect of gravitational convection on the regularities of exothermal reactions in tubular reactors,"Doklady Akad. Nauk SSSR 1977, 237, 1422.
  17. Davtyan, S. P.; Arutyunyan, K. A.; Shkadinskii, K. G.; Rozenberg, B. A.; Yenikolopyan, N. S. "The Mechanism of Epoxide oligomer hardening by diamines under advancing reaction front conditions,"Polymer Science U.S.S.R. 1978, 19, 3149-3154.
  18. Davtyan, S. P.; Gel'man, E. A.; Karyan, A. A.; Tonoyan, A. O.; Enikolopyan, N. S. "Applicability of the Principle of Quasistationary concentrations to the Radical Polymerization of vinyl monomers under Adiabatic Conditions,"Doklady Phys. Chem. 1980, 253, 579-582.
  19. Strunina, A. G.; Dvoryankin, A. V. Dokl. Phys. Chem. 1981, 260, 1185-1188.
  20. Gel'man, E. A.; Karyan, A. A.; Davtyan, S. P.; Vol'pert, A. I. "Applicability of Principle of Quasistationary concentrations in Calculating Molecular Weight Distribution for Processes of Radical Polymerization of Vinyl Monomers under nonisothermal Conditions,"Doklady Phys. Chem. 1981, 260, 971-974.
  21. Volpert, V. A.; Davtyan, S. P. "Wave existence in the simultaneous polymerization and crystallization,"Dokl. Akad. Nauk SSSR 1982, 268, 62-65.
  22. Gusika, P. L. "Theory of Polymerization Front Propagation in a Suspension,"Khim. Fiz. 1982, 7, 988-993.
  23. Volpert, V. A.; Davtyan, S. P. "Existence of the polymerization wave with crystallization of the initial substance,"Dokl. Akad. Nauk SSSR 1983, 273, 1155-1158.
  24. Begishev, V. P.; Volpert, V. A.; Davtyan, S. P.; Malkin, A. Y. "On some Features of the Anionic Activated e-Caprolactam Polymerization Process under Wave Propagation Conditions,"Dokl. Phys. Chem. 1985, 279, 1075-1077.
  25. Begishev, V. P.; Volpert, V. A.; Davtyan, S. P.; Malkin, A. Y. "On some Features of the Anionic Activated e-Caprolactam Polymerization Process under Wave Propagation Conditions,"Dokl. Phys. Chem. 1985, 279, 1075-1077.
  26. Begishev, V. P.; Davtjan, S. P.; Enikalopov, N .S. ; Malkin, A. Ya.; Frunze, T. V.; Kotelnikov, V. A. ; Avakjan, U. A.; Volpert, Vit. A. , "Method of Production of Block Polycaproamide," Patent No. 1155606 USSR, 1985.
  27. Volpert, V. A.; Mergabova, I. N.; Davtyan, S. P.; Begishev, V. P. "Propagation of the Caprolactam Polymerization Wave,"Combust. Explos. Shock Waves 1986, 21, 443-447.
  28. Zhizhin, G. V.; Segal, A. S.; Babadzhanyan, A. S.; Volpert, V. A.; Davtyan, S. P. "On Stationary States of Spherical and Cylindrical Front of the Reaction in Liquid with Variable Viscosity,"Kinet. Kataliz 1986, 27, 1310-1314.
  29. Babadzhanyan, A. S.; Volpert, V. A.; Davtyan, S. P. "Steady-State Modes of Frontal Polymerization in Radial Symmetric Delivery of the Monomer,"Dokl. Phys. Chem. 1987, 293, 357-360.
  30. Babadzhanyan, A. S.; Volpert, V. A.; Volpert, V. A.; Davtyan, S. P.; Megrabova, I. N. "Frontal Regimes of the Exothermic Reaction Proceeding by Radially Symmetrical Supply of Reagents,"Combust. Explos. Shock Waves 1988, 24, 711-719.
  31. Barelko, V. V.; Barkalov, I. M.; Goldanskii, V. I.; Kiryukhin, D. P.; Sanin, A. M. "Autowave Modes of Conversion in Low-Temperature Chemical Reactions in Solids," Adv. Chem. Phys. 1988, 74, 339-385.
  32. Babadzhanyan, A. S.; Volpert, V. A.; Volpert, V. A.; Davtyan, S. P.; Megrabova, I. N. "Stability of frontal regimes for the occurence of an exothermic reaction with radially symmetrical supply of the reagents,"Combust. Explos. Shock Waves 1989, 25, 23-31.
  33. Megrabova, I. N.; Volpert, V. A.; Volpert, V. A.; Davtyan, S. P. "Two-dimensional chemical reaction regimes in a flow,"Dokl. Phys. Chem. 1990, 307, 618-620.
  34. Pojman, J. A., "Traveling Fronts of Methacrylic Acid Polymerization," J. Am. Chem. Soc., 1991, 113, 6284-6286.
  35. Balcom, B. J.; Carpenter, T. A.; Hall, L. D. "Methacrylic Acid Polymerization. Travelling Waves Observed by Nuclear Magnetic Resonance Imaging,"Macromolecules 1992, 25, 6818-6823.
  36. Pojman, J. A.; Craven, R.; Khan, A.; West, W. "Convective Instabilities Induced by Traveling Fronts of Addition Polymerization," J. Phys. Chem., 1992, 96, 7466-7472.
  37. White, S. R.; Kim, C., Thermochemical modeling of an economical manufacturing technique for composite structures,37th Int. SAMPE Symp. Exhib., 1992, 240-251.
  38. Volpert, V. A.; Volpert, V. A.; Davtyan, S. P.; Mergabova, I. N.; Surkov, N. F. "Two-Dimensional Combustion Modes in Condensed Flow,"SIAM J. Appl. Math. 1992, 52, 368-383.
  39. White, S. R.; Kim, C. "A Simultaneous Lay-Up and in situ Cure Process for Thick Composites,"J. Reinforced Plastics and Comp. 1993, 12, 520-535.
  40. Pojman, J. A.; Nagy, I. P.; Salter, C. "Traveling Fronts of Addition Polymerization with a Solid Monomer,"J. Am. Chem. Soc. 1993, 115, 11044-11045.
  41. Korotkov, V. N.; Chekanov, Y. A.; Rozenberg, B. A. "The Simultaneous Process of Filament Winding and Curing for Polymer Composites,"Comp. Sci. & Tech. 1993, 47, 383-388.
  42. Solovyov, S. E.; Volpert, V. A.; Davtyan, S. P. "Radially Symmetric Flow of Reacting Liquid with Changing Viscosity,"SIAM J. Appl. Math. 1993, 53, 907-914.
  43. Volpert, Vit. A.; Volpert, Vl. A.; Pojman, J. A. "Effect of Thermal Expansion on Stability of Reaction Front Propagation," Chem. Eng. Sci. 1994, 14, 2385-2388.
  44. Volpert, V.; Volpert, V. "Propagation of Frontal Polymerization-Crystallization Waves,"Eur. J. Appl. Math. 1994, 5, 201-215.
  45. Savostyanov, V. S.; Kritskaya, D. A.; Ponomarev, A. N.; Pomogailo, A. D. "Thermally Initiated Frontal Polymerization of Transition Metal Nitrate Acrylamide Complexes,"J. Poly. Sci. Part A: Poly. Chem. 1994, 32, 1201-1212.
  46. Pojman, J. A.; Willis, J.; Fortenberry, D.; Ilyashenko, V.; Khan, A. "Factors Affecting Propagating Fronts of Addition Polymerization: Velocity, Front Curvature, Temperature Profile, Conversion and Molecular Weight Distribution," J. Polym. Sci. Part A: Polym Chem. 1995, 33, 643-652.
  47. Pojman, J. A.; Ilyashenko, V. M.; Khan, A. M. "Spin Mode Instabilities in Propagating Fronts of Polymerization," Physica D 1995, 84, 260-268.
  48. Nagy, I. P.; Sike, L.; Pojman, J. A. "Thermochromic Composite Prepared Via a Propagating Polymerization Front," J. Am. Chem. Soc. 1995, 117, 3611-3612.
  49. Ilyashenko, V.; Solovyov, S.; Pojman, J. A. "Theoretical Aspects of Self-Propagating Reaction Fronts in Condensed Medium," AIChE Journal 1995, 41, 2631-2636.
  50. Kim, C.; Teng, H.; Tucker, C. L.; White, S. R. "The Continuous Curing Process for Thermoset Polymer Composites. Part 1: Modeling and Demonstration,"J. Comp. Mater. 1995, 29, 1222-1253.
  51. Nagy, I. P.; Sike, L.; Pojman, J. A., "Thermochromic Composites and Propagating Polymerization Fronts," Adv. Mat. 1995, 7, 1038-1040.
  52. Szalay, J.; Nagy, I. P.; Barkai, I.; Zsuga, M. "Conductive Composites Prepared via a Propagating Polymerization Front,"Die Ang. Makr. Chem. 1996, 236, 97-109.
  53. Volpert, V.; Volpert, V. A.; Pojman, J. A.; Solovyov, S. E. "Hydrodynamic Stability of a Polymerization Front," Eur. J. Appl. Math. 1996, 7, 303-320.
  54. Garbey, M.; Taik, A.; Volpert, V. "Linear Stability Analysis of Reaction Fronts in Liquids,"Quart. Appl. Math. 1996, 54, 225-247.
  55. Pojman, J. A.;Willis, J. R.; Khan , A. M.; West, W. W., "The True Molecular Weight Distributions of Acrylate Polymers formed in Propagating Fronts," J. Polym. Sci. Part A: Polym Chem. 1996, 34, 991-995.
  56. Nagy, I. P.; Pojman, J. A., "Suppressing Convective Instabilities in Propagating Fronts by Tube Rotation," J. Phys. Chem. 1996, 100, 3299-3304.
  57. Volpert, V.; Volpert, V. A.; Pojman, J. A.; Solovyov, S. E. "Hydrodynamic Stability of a Polymerization Front,"Eur. J. Appl. Math. 1996, 7, 303-320.
  58. Pojman, J. A.; Ilyashenko, V. M.; Khan, A. M. "Free-Radical Frontal Polymerization: Self-Propagating Thermal Reaction Waves,"J. Chem. Soc. Faraday Trans. 1996, 92, 2824-2836.
  59. Pojman, J. A.; Curtis, G.; Ilyashenko, V. M. "Frontal Polymerization in Solution," J. Am. Chem. Soc. 1996, 115, 3783-3784.
  60. Khan, A. M.; Pojman, J. A. "The Use of Frontal Polymerization in Polymer Synthesis,"Trends Polym. Sci. (Cambridge, U.K.) 1996, 4, 253-257.
  61. Volpert, V. A.; Volpert, V. A.; Garbey, M.; Pojman, J. A. Stability of Reaction Fronts: in Gas-Phase Chemical Reaction Systems: Experiments and Models 100 Years after Max Bodenstein; Wolfrum, J.; Volpp, H.-R.; Rannacher, R. Warnatz, J., Ed.; Springer Berlin: Heidelberg, 1996; pp 309-317.
  62. Goldfeder, P. M.; Volpert, V. A.; Ilyashenko, V. M.; Khan, A. M.; Pojman, J. A.; Solovyov, S. E. "Mathematical Modeling of Free-Radical Polymerization Fronts,"J. Phys. Chem. B 1997, 101, 3474-3482.
  63. Pojman, J. A.; Elcan, W.; Khan, A. M.; Mathias, L. "Binary Polymerization Fronts: A New Method to Produce Simultaneous Interpenetrating Polymer Networks (SINs),"J. Polym. Sci. Part A: Polym Chem. 1997, 35, 227-230.
  64. Apostolo, M.; Tredici, A.; Morbidelli, M.; Varma, A. "Propagation Velocity of the Reaction Front in Addition Polymerization Systems,"J. Polym. Sci. Part A: Polym Chem. 1997, 35, 1047-1059.
  65. Bowden, G.; Garbey, M.; Ilyashenko, V. M.; Pojman, J. A.; Solovyov, S.; Taik, A.; Volpert, V. "The Effect of Convection on a Propagating Front with a Solid Product: Comparison of Theory and Experiments,"J. Phys. Chem. B 1997, 101, 678-686.
  66. Solovyov, S. E.; Ilyashenko, V. M.; Pojman, J. A. "Numerical Modeling of Self-Propagating Fronts of Addition Polymerization: The Role of Kinetics on Front Stability," Chaos 1997, 7, 331-340.
  67. Pojman, J. A.; West, W. W.; Simmons, J. "Propagating Fronts of Polymerization in the Physical Chemistry Laboratory," J. Chem. Ed. 1997, 74, 727-730.
  68. Pojman, J.; Fortenberry, D.; Ilyashenko, V. "Frontal Polymerization as an Analog of SHS," Int. J. Self-Propag. High-Temp. Synth. 1997, 6, 355-376.
  69. Chekanov, Y.; Arrington, D.; Brust, G.; Pojman, J. A. "Frontal Curing of Epoxy Resin: Comparison of Mechanical and Thermal Properties to Batch Cured Materials,"J. Appl. Polym. Sci. 1997, 66, 1209-1216.
  70. Pojman, J. A.; Khan, A. M.; Mathias, L. J. "Frontal Polymerization in Microgravity: Results from the Conquest I Sounding Rocket Flight,"Microg. sci. technol. 1997, X, 36-40.
  71. Galyagin, K. S.; Vakhrameev, E. I. "Numerical Calculation of the Frontal Polymerisation of a Thermoplastic in a Cylindrical Reactor," International Polymer Science and Technology 1997, 25(5), 35-38.
  72. Coons, L. S.; Rangarajan, B.; Godshall, D.; Scranton, A. B. Photopolymerization of Vinyl Ester: Glass Fiber Composites: in Photopolymerization: Fundamentals and Applications, ACS Symposium Series 673; Scranton, A. B.; Bowman, C. N. Peiffer, R. W., Ed.; American Chemical Society: Washington, DC, 1997; pp 203-218.
  73. Tredici, A.; Pechhini, R.; Sliepcevich, A.; Morbidelli, M. "Polymer Blends by Self-Propagating Frontal Polymerization,"J. Appl. Polym. Sci. 1998, 70, 2695-2702.
  74. Tredici, A.; Pecchini, R.; Morbidelli, M. "Self-Propagating Frontal Copolymerization," J. Polym. Sci. Part A: Polym Chem. 1998, 36, 1117-1126.
  75. Volpert, V. A.; Volpert, V. A.; Ilyashenko, V. M.; Pojman, J. A. "Frontal Polymerization in a Porous Medium,"Chem. Eng. Sci. 1998, 53, 1655-1665.
  76. Fortenberry, D. I.; Khan, A.; Ilyashenko, V. M.; Pojman, J. A. Frontal Polymerization: Self-Propagating High Temperature Synthesis of Polymeric Materials: in Synthesis and Characterization of Advanced Materials, ACS Symposium Series No. 681; Serio, M. A.; Gruen, D. M. Malhotra, R., Ed.; American Chemical Society: Washington, DC, 1998; pp 220-235.
  77. Volpert, Vit; Volpert, Vl.; Ilyashenko, V.; Pojman, J. A. "Frontal Polymerization in a Porous Medium," Chem. Eng. Sci. 1998, 53, 1655-1665.
  78. Ilyashenko, V. M.; Pojman, J. A. "Single Head Spin Modes in Frontal Polymerization,"Chaos 1998, 8, 285-289.
  79. Masere, J.; Pojman, J. A. "Free Radical-Scavenging Dyes as Indicators of Frontal Polymerization Dynamics,"J. Chem. Soc. Faraday Trans. 1998, 94, 919-922.
  80. McCaughey, B.; Pojman, J. A.; Simmons, C.; Volpert, V. A. "The Effect of Convection on a Propagating Front with a Liquid Product: Comparison of Theory and Experiments,"Chaos 1998, 8, 520-529.
  81. Pojman, J. A.; Gunn, G.; Patterson, C.; Owens, J.; Simmons, C. "Frontal Dispersion Polymerization," J. Phys. Chem. B; 1998, 102, 3927-3929.
  82. Goldfeder, P. M.; Volpert, V. A. "Nonadiabatic frontal polymerization,"J. Eng. Math. 1998, 34, 301-318.
  83. Goldfeder, P. M.; Volpert, V. A. "A model of frontal polymerization including the gel effect,"Math. Problems in Engin. 1998, 4, 377-391.
  84. Galgyin, K. S.; Vakhrameev, E. L. "Numerical Calculation of the Frontal Polymerisation of a Thermoplastic in a Cylindrical Reactor," International. Polym. Sci. & Tech. 1998, 25, 35-38.
  85. Masere,J.; Stewart, F.; Meehan, T.; Pojman, J. A. "Period-doubling Behavior in Frontal Polymerization of Multifunctional Acrylates," Chaos, 1999, 9, 315-322
  86. Pojman, J. A.; Fortenberry, D.; Lewis, L. L.; Simmons, C.; Ilyashenko, V. Solvent-Free Synthesis by Free-Radical Frontal Polymerization: in Solvent-Free Polymerizations and Processes, ACS Symposium Series No. 713; Long, T. E. Hunt, M. O., Ed.; American Chemical Society: Washington, D.C., 1998; pp 140-153.
  87. Garbey, M.; Tromeur-Dervout, D. "A New Parallel Solver for the Nonperiodic Incompressible Navier-Stokes Equations with a Fourier Method: Application to Frontal Polymerization,"J. Comp. Phys. 1998, 145, 316-331.
  88. Barelko, V. V.; Pomogailo, A. D.; Dzhardimalieva, G. I.; Evstratova, S. I.; Rozenberg, A. S.; Uflyand, I. E. "The Autowave Modes of Solid Phase Polymerization of Metal-Containing Monomers in Two- and Three-Dimensional Fiberglass-Filled Matrices,"Chaos 1999, 9, 342-347.
  89. Szalay, J.; Nagy, I.; Bayai, I.; DeaK, G.; Bazsa, G.; Zsuga, M. "High Temperature Copolymerization of Styrene and Maleic Anhydride in Propagating Polymerization Front," Macromol. Rapid Comm. 1999, 20, 315-318.
  90. Goldfeder, P. M.; Volpert, V. A. "A Model of Frontal Polymerization Using Complex Initiation," Math. Problems in Enginering 1999, 5, 139-160.
  91. Schult, D. A.; Volpert, V. A. "Linear Stability Analysis of Thermal Free Radical Polymerization Waves,"Int. J. Self-Propag. High-Temp. Synth. 1999, 8, 417-440.
  92. Kiryukhin, D. P.; Barelko, V. V.; Barkalov, I. M. "Traveling Waves of Cryochemical Reaction in Radiolyzed Systems (Review)," High Energy Chemistry 1999, 33, 133-144.
  93. Spade, C. A.; Volpert, V. A. "On The Steady State Approximation in Thermal Free Radical Frontal Polymerization,"Chem. Eng. Sci. 2000, 55, 641-654.
  94. Fortenberry, D. I.; Pojman, J. A. "Solvent-Free Synthesis of Polyacrylamide by Frontal Polymerization,"J. Polym. Sci. Part A: Polym Chem. 2000, 38, 1129-1135
  95. Texier-Picard, R.; Pojman, J. A.; Volpert, V. A. "Effect of Interfacial Tension on Propagating Polymerization Fronts,"Chaos 2000, 10, 224-230.
  96. Masere, J.; Chekanov, Y..; Warren, J. R.; Stewart, F.; Al-Kaysi, R.; Rasmussen, J. K.; Pojman, J. A. "Gas-free Initiators for High-Temperature Polymerization,"J. Poly. Sci. Part A. Polym. Chem. 2000, 38,  3984-3990.
  97. Chekanov, Y. A.; Pojman, J. A. "Preparation of Functionally Gradient Materials Via Frontal Polymerization,"J. Appl. Polym. Sci. 2000, 78, 2398-2404.
  98. Kiryukhin, D. P.; Barkalov, I. M. "The Autowave Regimes of Cryopolymerization," Polymer Science Series B 2000, 42, 244-253.
  99. Rosell, A.; Storti, G.; Morbidelli, M. "Reaction Propagation in Frontal Polymerization," DECHEMA Monographien 2001, 137, 487-494.
  100. Manz, B.; Masere, J.; Pojman, J. A.; Volke, F. "Magnetic Resonance Imaging of Spiral Patterns in Crosslinked Polymer Gels Produced via Frontal Polymerization,"J. Poly. Sci. Part A. Polym. Chem. 2001, 39, 1075-1080.
  101. Allali, K.; Pojman, J.; Volpert, V. "Influence of Vibrations on Convective Instability of Polymerization Fronts,"J. Eng. Math. 2001, 41, 13-31.
  102. Ainsworth, W.; Pojman, J. A.; Chekanov, Y.; Masere, J. Bubble Behavior in Frontal Polymerization: Results from KC-135 Parabolic Flights: in Polymer Research in Microgravity: Polymerization and Processing, ACS Symposium Series No. 793; Downey, J. P. Pojman, J. A., Ed.; American Chemical Society: Washington, DC, 2001; pp 112-125.
  103. Mariani, A.; Fiori, S.; Chekanov, Y.; Pojman, J. A. "Frontal Ring-Opening Metathesis Polymerization of Dicyclopentadiene,"Macromolecules 2001, 34, 6539-6541.
  104. Washington, R. P.; Steinbock, O. "Frontal Polymerization Synthesis of Temperature-Sensitive Hydrogels,"J. Am. Chem. Soc. 2001, 123, 7933-7934.
  105. Spade, C. A.; Volpert, V. A. "Linear Stability Analysis of Nonadiabatic Free Radical Polymerization Waves,"Combustion Theory and Modelling 2001, 5, 21-39.
  106. Davtyan, D. S.; Bagdasaryan, A. E.; Tonoyan, A. O.; Davtyan, S. P. "To the Contribution of Thermal Convective Mass Transfer fo the Reactive Mixture Components to Frontal Curing of Epoxydiane Oligomers," Chem. Phys. Reports 2001, 19, 1757-1765.
  107. Davtyan, S. P.; Hambartsumyan, A. F.; Davtyan, D. S.; Tonoyan, A. O.; Hayrapetyan, S.; Bagyan, S. H.; Manukyan, L. S. "The Structure, Rate and Stability of Autowaves During Polymerization of Co Metal-Complexes with Acrylamide," European Polymer Journal 2002, 38, 2423-2431.
  108. Pojman, J. A.; Masere, J.; Petretto, E.; Rustici, M.; Huh, D.-S.; Kim, M. S.; Volpert, V. "The Effect of Reactor Geometry on Frontal Polymerization Spin Modes,"Chaos 2002, 56-65.
  109. Bazile Jr., M.; Nichols, H. A.; Pojman, J. A.; Volpert, V. "The Effect of Orientation on Thermoset Frontal Polymerization,"J. Polym. Sci. Part A: Polym Chem. 2002, 40, 3504-3508.
  110. Pojman, J. A.; Volpert, V. A.; Volpert, V. A. "Nonlinear Dynamics of SHS-Like Processes in Polymer Chemistry" in Self-Propagating High-Temperature Synthesis of Materials; A. A. Borisov, L. T. De Luca., A. G. Merzhanov, Ed.; Taylor and Francis:  New York, 2002; pp 99-118.
  111. Fiori, S.; Mariani, A.; Ricco, L.; Russo, S. "Interpenetrating Polydicyclopentadiene/Polyacrylate Networks Obtained by Simultaneous Non-interfering Frontal Polymerization,"e-Polymers 2002, 29, 1-10.
  112. Fiori, S.; Malucelli, G.; Mariani, A.; Ricco, L.; Casazza, E. "Synthesis and Characterization of a Polyester/Styrene Resin obtained by Frontal Polymerization," e-Polymers 2002, 57, 1-10.
  113. Dzhardimalieva, G. I.Pomogailo, A.D.; Volpert, Vit .A. "Frontal Polymerization of Metal-Containing Monomers: A Topical Review,"Journal of Inorganic and Organometallic Polymers 2002, 12, 1-21.
  114. Gill, N.; Pojman, J. A.; Willis, J.; Whitehead, J. B. "Polymer Dispersed Liquid Crystal (PDLC) Materials Fabricated Using Frontal Polymerization,"J. Poly. Sci. Part A. Polym. Chem. 2003, 41, 204-212
  115. Perry, M.F.; Volpert, Vl, A; Lewis, L. L.; Nichols, H. A.; Pojman, J. A. "Free-radical Frontal Copolymerization: The Dependence of the Front Velocity on the Monomer Feed Composition and Reactivity Ratios," Macromolecular Theory and Simulations 2003, 12, 276-286.
  116. Fiori, S.; Mariani, A.; Ricco, L.; Russo, S., "First Synthesis of a Polyurethane by Frontal Polymerization," Macromolecules 2003, 36, 2674-2679.
  117. Mariani, A.; Bidali, S.; Fiori, S.; Malucelli, G.; Sanna, E. "Synthesis and Characterization of a Polyurethane Prepared by Frontal Polymerization,"e-Polymers 2003, 44, 1-9.
  118. Washington, R. P.; Steinbock, O. "Frontal Free-Radical Polymerization: Applications to Materials Synthesis," Polymer News 2003, 28, 303-310.
  119. Bidali, S.; Fiori, S.; Malucelli, G.; Mariani, A. "Frontal Atom Transfer Radical Polymerization of Tri-ethylene glycol) Dimethacrylate," e-Polymers 2003, 60, 1-12.
  120. Huh, D. S.; Kim, H. S. "Bistability of Propagating Front with Spin-mode in a Frontal Polymerization of Trimethylopropane Triacrylate,"Polymer International 2003, 52, 1900-1904.
  121. Ritter, I. R.; Olmstead, W. E.; Volpert, V. A. "Initiation of Free-radical Polymerization Waves," Siam J. Appl. Math. 2003, 63, 1831-1848.
  122. Gross, L. K.; Volpert, V. A. "Weakly Nonlinear Stability Analysis of Frontal Polymerization, " Studies in Appl. Math. 2003, 110, 351-376.
  123. Pojman, J. A.; Popwell, S.; Fortenberry, D. I.; Volpert, V. A.; Volpert, V. A. Nonlinear Dynamics in Frontal Polymerization: in Nonlinear Dynamics in Polymeric Systems, ACS Symposium Series No. 869; Pojman, J. A. Tran-Cong-Miyata, Q., Ed.; American Chemical Society: Washington, DC, 2003; pp 106-120.
  124. Mariani, A.; Fiori, S.; Malucelli, G. Recent Chemical Advances in Frontal Polymerization: in Nonlinear Dynamics in Polymeric Systems, ACS Symposium Series No. 869; Pojman, J. A. Tran-Cong-Miyata, Q., Ed.; American Chemical Society: Washington, DC, 2003; pp 121-134.
  125. Commissiong, D. M. G.; Gross, L. K.; Volpert, V. A. Bifurcation Analysis of Polymerization Fronts: in Nonlinear Dynamics in Polymeric Systems, ACS Symposium Series No. 869; Pojman, J. A. Tran-Cong-Miyata, Q., Ed.; American Chemical Society: Washington, DC, 2003; pp 147-159.
  126. Asakara, K.; Nihei, E.; Harasawa, H.; Ikumo, A.; Osanai, S. Spontaneous Frontal Polymerization: Propagating Front Spontaneously Generated by Locally Autoaccelerated Free-Radical Polymerization: in Nonlinear Dynamics in Polymeric Systems, ACS Symposium Series No. 869; Pojman, J. A. Tran-Cong-Miyata, Q., Ed.; American Chemical Society: American Chemical Society, 2003; pp 135-146.
  127. Dzhardimalieva, G. I.; Golubeva, N. D.; Pomogailo, A. D. "Frontal Polymerization of Metal-Containing Monomers as a way for Synthesis of Polymer Nanocomposites," Diffusion and Defect Data Part B Solid State Phenomena 2003, 94, 323-328.
  128. Kiryukhin, D. P.; Barkalov, I. M. "Chain Chemical Reactions at Low Temperature," Russian Chemical Reviews 2003, 72, 217-231.
  129. Fiori, S.; Mariani, A.; Bidali, S.; Malucelli, G. "Synthesis and Characterization of Unsaturated Polyester Resins Cured by Frontal Polymerization,"e-Polymers 2004, 1, 1-12.
  130. Pojman, J. A.; Varisli, B.; Perryman, A.; Edwards, C.; Hoyle, C. "Frontal Polymerization with Thiol-Ene Systems," Macromolecules 2004, 37, 691-693.
  131. Pojman, J. A.; Griffith, J.; Nichols, H. A. "Binary Frontal Polymerization: Velocity Dependence on Initial Composition," e-Polymers 2004, 13, 1-7.
  132. Mariani, A.; Bidali, S.; Fiori, S.; Sangermano, M.; Malucelli, G.; Bongiovanni, R.; Priola, A. "UV-Ignited Frontal Polymerization of an Epoxy Resin," J. Poly. Sci. Part A. Polym. Chem. 2004, 42, 2066-2072.
  133. Crivello, J. V.; Falk, B.; Zonca Jr., M. R. "Photoinduced Cationic Ring-Opening Frontal Polymerizations of Oxetanes and Oxiranes," J. Poly. Sci. Part A. Polym. Chem. 2004, 42, 1630-1646.
  134. Kholpanov, L. P.; Zakiev, S. E.; Pomogailo, A. D. "Modeling of Frontal Polymerization with Consideration of Phase Transitions in the Reaction Front," Doklady Physical Chemistry 2004, 395, 84-87.
  135. Pomogailo, A. D.; Dzhardimalieva, G. I. "Frontal Polymerization of Metal-Containing Monomers: Achievements and Problems," Polymer Science Series A 2004, 46, 250-263.
  136. Perry, M. F.; Volpert, V. A. "Self-propagating Free-radical Binary Frontal Polymerization," Journal of Engineering Mathematics 2004, 49, 359-372.
  137. Pujari, N. S.; Vishwakarma, A. R.; Kelkar, M. K.; Ponrathnam, S. "Gel Formation in Frontal Polymerization of 2-Hydroxyethyl Methacrylate," e-Polymers 2004, 049, 1-10.
  138. Shkadinskaya, G. V.; Shkadinskii, K. G. "Filtration Mechanism of Propagation of Frontal Polymerization," Doklady Physical Chemistry 2004, 397, 161-165.
  139. Perry, M. F.; Volpert, V. A. "Linear Stability Analysis of Two Monomer Systems of Frontal Polymerization," Chemical Engineering Science 2004, 59, 3451-3460.
  140. Texter, J.; Ziemer, P. "Polyurethanes via Microemulsion Polymerization," Macromolecules 2004, 37, 5841-5843.
  141. McFarland, B.; Popwell, S.; Pojman, J. A. "Free-Radical Frontal Polymerization with a Microencapsulated Initiator," Macromolecules 2004, 37, 6670 - 6672.
  142. Pujari, N. S.; Vishwakarma, A. R.; Pathak, T. S.; Mule, S. A.; Ponrathnam, S. "Frontal Copolymerization of 2-Hydroxyethyl Methacrylate and Ethylene Glycol Dimethacrylate without Porogen: Comparison with Suspension Polymerization," Polym. Intern. 2004, 53, 2045-2050.
  143. Mariani, A. F., S.; Bidali, S.; Fiori, S.; Malucelli, G.; Ricco, L. "New Vistas in Frontal Polymerization," Macromol. Symp. 2004, 218, 1-9.
  144. Pujari, N. S.; Vishwakarma, A. R.; Pathak, T. S.; Kotha, A. M.; Ponrathnam, S. "Functionalized Polymer Networks: Synthesis of Microporous Polymers by Frontal Polymerization," Bulletin of Materials Science 2004, 27, 529-536.
  145. Chen, S.; Sui, J.; Chen, L.; Pojman, J. A. "Polyurethane-Nanosilica Hybrid Nanocomposites Synthesized by Frontal Polymerization," J. Polym. Sci. Part A Polym. Chem. 2005, 43, 1670-1680.
  146. Vicini, S.; Mariani, A.; Princi, E.; Bidali, S.; Pincin, S.; Fiori, S.; Pedemonte, E.; Brunetti, A. "Frontal Polymerization of Acrylic Monomers for the Consolidation of Stone," Polymers for Advanced Technologies 2005, 16, 293 - 298.
  147. Chen, S.; Feng, C.; Sui, J. "Study on Frontal Polymerization of Polyurethane/Nanosilica Sol Hybrids," Acta Polymerica Sinica 2005, 1, 1-3.
  148. Frulloni, E.; Salinas, M. M.; Torre, L.; Mariani, A.; Kenny, J. M. "Numerical Modeling and Experimental Study of the Frontal Polymerization of the Diglycidyl Ether of Bisphenol a/Diethylenetriamine Epoxy System," J. Appl. Polym. Sci. 2005, 96, 1756-1766.
  149. Chen, S. H.; Sui, J.; Chen, L. "Segmented Polyurethane Synthesized by Frontal Polymerization," Colloid and Polymer Science 2005, 283, 932-936.
  150. Nason, C.; Roper, T.; Hoyle, C.; Pojman, J. A."UV-Induced Frontal Polymerization of Multifunctional (Meth)Acrylates," Macromolecules 2005, 38, 5506-5512.
  151. Bidali, S.: Ducrot,, A.; Mariani, A.; Rustici, M. "Self-ignition of Polymerization Fronts with Convection: The 'Rainstorm Effect'," e-Polymers, 2005, 44, 1-18.
  152. Cardarelli, S. A.; Golovaty, .D; Gross, L. K.; Gyrya, V. T.; Zhu, J. "A Numerical Study of One-step Models of Polymerization: Frontal versus Bulk Mode," Physica D, 2005, 206, 145-165.
  153. Falk, B.; Zonca, M. R.; Crivello, J. V. "Photoactivated Cationic Frontal Polymerization," Macromolecular Symposia 2005, 226, 97-108.
  154. Lovrity, Z.; Nagy, I.; Gacsi, Z.; Barany, Z. B. "Preparation of Polymer-metal Composites via In-situ Decomposition of Metal Salts by Frontal Polymerization," Muanyag Es Gumi, 2005, 42, 324-327.
  155. Yan, Q. Z.; Su, X. T.; Zhang, W. F.; Ge, C. C. "Preparation of Starch-G-Sodium Acrylate/Acrylamide Superabsorbent Via Frontal Polymerization," Chemical Journal of Chinese Universities 2005, 26, 1363-1365.
  156. Comissiong, D.; Gross, L.; Volpert, V. "Nonlinear Dynamics of Frontal Polymerization with Autoacceleration," J. Enging. Mathematics 2005, 53, 59-78.
  157. Crivello, J. V.; Bulut, U. "Photoactivated Cationic Ring-Opening Frontal Polymerizations of Oxetanes," Designed Monomers & Polymers 2005, 8, 517-531.
  158. Crivello, J. V. "Investigation of the Photoactivated Frontal Polymerization of Oxetanes Using Optical Pyrometry," Polymer 2005, 46, 12109-12117.
  159. Qingzhi, Y.; Xintai, S.; Changchun, G. "Recent Developments of Self-Propagating Frontal Polymerization," Progress in Chemistry 2005, 17, 1081-1088.
  160. Yan, Q.-Z.; Zhang, W.-F.; Lu, G.-D.; Su, X.-T.; Ge, C.-C. "Frontal Copolymerization Synthesis and Property Characterization of Starch-Graft-Poly(Acrylic Acid) Hydrogels," Chem. Eur. J. 2005, 12, 6609-6615.
  161. Devadoss, D. E.; Pojman, J. A.; Volpert, V. A. "Mathematical Modeling of Thiol-Ene Frontal Polymerization," Chem. Eng. Sci. 2006, 61, 1257-1271.
  162. Binici, B.; Fortenberry, D. I.; Leard, K. C.; Molden, M.; Olten, N.; Popwell, S.; Pojman, J. A. "Spherically Propagating Thermal Polymerization Fronts," J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 1387-1395.
  163. McFarland, B.; Popwell, S.; Pojman, J. A. "Free-Radical Frontal Polymerization with a Microencapsulated Initiator: Characterization of Microcapsules and Their Effect on Pot Life, Front Velocity and Mechanical Properties," Macromolecules 2006, 39, 53-63.
  164. Kholpanov, L. P.; Zakiev, S. E.; Pomogailo, A. D. "Two-Phase Frontal Polymerization of Metal-Containing Monomers," Polymer Science Series A 2006, 48, 11-17.
  165. Hu, T.; Chen, S.; Tian, Y.; Pojman, J. A.; Chen, L. "Frontal Free-Radical Copolymerization of Urethane-Acrylates," J. Poly. Sci. Part A. Polym. Chem. 2006, 44, 3018-3024.
  166. Chen, S.; Tian, Y.; Chen, L.; Hu, T. "Epoxy Resin/Polyurethane Hybrid Networks Synthesized by Frontal Polymerization," Chem. Mater. 2006, 18, 2159-2163.
  167. Yan, Q.; Zhang, W. F.; Lu, G. D.; Su, X. T.; Ge, C. C. "Frontal Polymerization Synthesis of Starch-Grafted Hydrogels: Effect of Temperature and Tube Size on Propagating Front and Properties of Hydrogels," Chem. Eur. J2006, 12, 3303-3309.
  168. Davtyan, S. P.; Tonoyan, A. O.; Tataryan, A. A.; Schick, C. "Interphase Phenomena in Superconductive Polymer-Ceramic Nanocomposites," Composite Interfaces 2006, 13, 535-544.
  169. Commissiong, D. M. G.; Gross, L. K.; Volpert, V. A. "Frontal Polymerization in the Presence of an Inert Material," J. Engin. Math. 2006, 54, 389-402.
  170. Jeszenszky, A.; Szabo, S.; Nagy, I. P. " Comparative Review on SHS Thermodynamics Applied for Frontal Polymerization of Acrylamide and Triethylene Glycol Dimethacrylate," Polym. Journal 2006, 38, 364-368.
  171. Crivello, J. V. "Design and Synthesis of Multifunctional Glycidyl Ethers That Undergo Frontal Polymerization," J. Poly. Sci. Part A. Polym. Chem. 2006, 44, 6435-6448.
  172. Cui, Y.; Yang, J.; Zeng, Z.; Chen, Y. "Advances on the Investigation and Application of Frontal Polymerization-Part A," Polymer Bulletin 2006 ,57, 53-58.
  173. Cui, Y.; Yang, J.; Zeng, Z.; Chen, Y. "Advances on the Investigation and Application of Frontal Polymerization-Part B," Polymer Bulletin 2006, 8, 44-51.
  174. Sˆ„wka, E.; Leonowicz, M.; Ka¬¥zmierczak, J.; ¬¥Slawska-Waniewska, A.; Pomogailo, A. D.; Dzhardimalievac, G. I. "Formation of Cobalt Nanoparticles in Inorganic Matrix by Frontal
    Polymerisation and Thermolysis of Metal-Containing Monomers," Physica B 2006, 384, 282’Äì285.
  175. Proietti, N.; Capitani, D.; Cozzolino, S.; Valentini, M.; Pedemonte, E.; Princi, E.; Vicini, S.; Segre, A. L. "In Situ and Frontal Polymerization for the Consolidation of Porous Stones: A Unilateral NMR and Magnetic Resonance Imaging Study," J. Phys. Chem. B 2006, 110, 23719-23728.
  176. Xiaobin, W. H., F.; Hong, H. "Frontal Polymerization and Its Application in Synthesis of Functional Polymer," Modern Plastics Processing and Applications 2006, 18, 56-58.
  177. Hu, T.; Chen, S.; Tian, Y.; Chen, L.; Pojman, J. A. "Facile Synthesis of Poly (Hydroxyethyl Acrylate) by Frontal Free-Radical Polymerization," J. Polym. Sci. Part A Polym. Chem. 2007, 45, 873-881.
  178. Pujari, N. S.; Inamdar, S. R.; Ponrathnam, S.; Kulkarni, B. D. "Water-Triggered Frontal Polymerization," Macromolecular Rapid Communications 2007, 28, 109-115.
  179. Inamdar, S. R.; Pujari, N.; Karimi, I. A.; Ponrathnam, S.; Tayal, R. K.; Kulkarni, B. D. "Spinning Wave Motion in Frontal Polymerization," Chem. Eng. Sci. 2007, 62, 1448-1455.
  180. Comissiong, D.; Gross, L.; Volpert, V. "The Enhancement of Weakly Exothermic Polymerization Fronts," J. Engin. Math. 2007, 57, 423-435.
  181. Mariani, A.; Bidali, S.; Caria, G.; Monticelli, O.; Russo, S.; Kenny, J. M. "Synthesis and Characterization of Epoxy Resin- Montmorillonite Nanocomposites Obtained by Frontal Polymerization," J. Polym. Sci. Part A Polym. Chem. 2007, 45, 2204’Äì2211.
  182. Hu, T.; Fang, Y.; Yu, H.; Chen, L.; Chen, S. "Synthesis of Poly(N-Methylolacrylamide)/Polymethylacrylamide Hybrids Via Frontal Free-Radical Polymerization," Colloid and Polymer Science 2007, 285, 891-898.
  183. Lu, G. D.; Yan, Q. Z.; Ge, C. C. "Preparation of Porous Polyacrylamide Hydrogels by Frontal Polymerization," Polym. Intern. 2007, 56, 1016-1020.
  184. Crivello, J. V. "Hybrid Free Radical/Cationic Frontal Photopolymerizations," J. Polym. Sci. Part A Polym. Chem. 2007, 45, 4331’Äì4340.
  185. Mariani, A.; Alzari, V.; Monticelli, O.; Pojman, J. A.; Caria, G. "Polymeric Nanocomposites Containing Polyhedral Oligomeric Silsesquioxanes (Poss) Prepared Via Frontal Polymerization," J. Polym. Sci. Part A Polym. Chem. 2007, 45, 4514-4521.
  186. Chen, S.; Hu, T.; Yu, H.; Chen, L.; Pojman, J. A. "First Solvent-Free Synthesis of Poly (N-Methylolacrylamide) Via Frontal Free Radical Polymerization," J. Polym. Sci. Part A Polym. Chem. 2007 ,45, 4322 - 4330.
  187. Morgunov, R.; Dmitriev, A.; Dzhardimalieva, G. I.; Pomogailo, A. D. "Ferromagnetic Resonance of Cobalt Nanoparticles in the Polymer Shell," Physics of the Solid State 2007, 49, 1507-1513.
  188. Pojman, J. A.; Viner, V.; Binici, B.; Lavergne, S.; Winsper, M.; Golovaty, D.; Gross, L. "Snell’s Law of Refraction Observed in Thermal Frontal Polymerization," Chaos 2007, 17, 033125.
  189. Barany, Z. B.; Nagy, I. P.; Lovrity, Z.; Gacsi, Z. "Preparation of Polymer-Metal Composites Via in Situ Decomposition of Metal Salts by Frontal Polymerization," Macromolecular Reaction Engineering 2007, 1, 40-44.
  190. Brunetti, A.; Mariani, A.; Bidali, S. "X-Ray Tomography as an Estimation Technique for Wood Consolidation by Frontal Polymerization," Nuovo Cimento- Societa Italiana di Fisica Sezione C 2007, 30, 407-416.
  191. Cai, X.; Chen, S.; Chen, L. "Solvent-Free Free-Radical Frontal Polymerization: A New Approach to Quickly Synthesize Poly(N-Vinylpyrrolidone)," J. Polym. Sci. Part A Polym. Chem. 2008, 46, 2177-2185.
  192. Alberto Mariani, S. F. S. B. V. A. G. M. "Frontal Polymerization of Diurethane Diacrylates,"" J. Polym. Sci. Part A Polym. Chem. 2008, 46, 3344-3352.

 

Patents Related to Frontal Polymerization

Dixon, G. D., "In Depth Curing of Resins Induced by Uv Radiation," 1980, U. S. Patent, 4,222,835.

Pojman, J. A.; McCardle, T. W. "Functionally Gradient Polymeric Materials," 2000, U.S. Patent 6,057,406.


Pojman, J. A.; McCardle, T. W. "Functionally Gradient Polymeric Materials," 2001, U.S. Patent 6,313,237.

Gregory, S., "Ultraviolet curable resin compositions having enhanced shadow cure properties," 2001, U.S. Patent 6,245,827.


Pfeil; A ; Burgel; T.; Morbidelli; M.; Rosell; A.," Mortar composition, curable by frontal polymerization, and a method for fastening tie bars," 2003, U.S. Patent 6,533,503

Burgel, T.; Marianne, B., "Mortar Composition of at Least Two Components and Curable by Heat Initiation and a Method for Fastening Tie Rods, Reinforcing Steel for Concrete or the Like in Solid Substrates," 2004, US Patent, 6,815,517.

Pojman, J. A.; McFarland, B.; Popwell, S. "Free-radical frontal polymerization with microencapsulated monomers and initiators" US Patent Pending.

 

Isothermal Frontal Polymerization ( Interfacial Gel Polymerization)

  1. Koike, Y.; Takezawa, Y.; Ohtsuka, Y. "New Interfacial-Gel Copolymerization Techniques for Steric GRIN Polymer Optical Waveguides and Lens Arrays,"Appl. Opt. 1988, 27, 486-491.
    Golubev, V. B.; Gromov, D. G.; Korolev, B. A. "The Mechanism of Frontal Polymerization of Methyl Methacrylate,"J. Appl. Polymer Science 1992, 46, 1501-1502.
  2. Gromov, D. G.; Frisch, H. L. "A simple Mathematical Model of Frontal Polymerization,"J. Appl. Polymer Science 1992, 46, 1499-1500.
  3. Koike, Y. Gradient Index Materials and Components: in Polymers for Lightwave and Integrated Optics; Hornak, L. A., Ed.; Marcel Dekker: New York, 1992; pp 71-104.
  4. Smirnov, B. R. M. k., S. S.; Lusinov, I. A.; Sidorenko, A. A.;Stegno, E. V.; Ivanov, V. V. "Frontal radical polymerization in the presence of a polymeric inhibitor,"Vysokomol. Soedin., Ser. B 1993, 35, 161-162.
  5. Zhang, Q.; Wang, P.; Zhai, Y. "Refractive Index Distribution of Graded Index Poly(methyl methacrylate) Preform Made by Interfacial-Gel Polymerization,"Macromolecules 1997, 30, 7874-7879.
  6. Spade, C. A.; Volpert, V. A. "Mathematical Modeling of Interfacial Gel Polymerization,"Mathematical and Computer Modelling 1999, 30, 67-73.
  7. Spade, C. A.; Volpert, V. A. "Mathematical Modeling of Interfacial Gel Polymerization for Weak and Srtong Gel Effects,"Macromol. Theory Simul. 2000, 9, 26-46.
  8. Masere, J.; Lewis, L. L.; Pojman, J. A. "Optical Gradient Materials Produced Via Low-Temperature Isothermal Frontal Polymerization,"J. Appl. Polym. Sci. 2001, 80, 686-691.
  9. Ivanov, V. V.; Stegno, E. V.; Pushchaeva, L. M. "Influence of Reaction Conditions on the Frontal Polymerization of Methyl Methacrylate," Polym. Sci. Ser. A 2002, 44, 1017-1022.
  10. Lewis, L. L.; DeBisschop, C. A.; Pojman, J. A.; Volpert, V. A. Evolution of Isothermal Polymerization Fronts via Laser Line Deflection and Predictive Modeling: in Nonlinear Dynamics in Polymeric Systems, ACS Symposium Series No. 869; Pojman, J. A. Tran-Cong-Miyata, Q., Ed.; American Chemical Society: Washington, DC, 2003; pp 169-185.
  11. Lewis, L. L.; DeBisschop, C. S.; Pojman, J. A.; Volpert4, V. A. "Isothermal Frontal Polymerization: Confirmation of the Mechanism and Determination of Factors Affecting Front Velocity, Front Shape, and Propagation Distance with Comparison to Mathematical Modeling,"J. Polym. Sci. Part A Polym. Chem. 2005, 43, 5774-5786.
  12. Devadoss, D. E.; Volpert, V. A. "Modeling Isothermal Free-Radical Frontal Polymerization with Gel Effect Using Free Volume Theory, with and without Inhibition," J. Mathematical Chem. 2006, 39, 73-104.
  13. Evstratova, S. I.; Antrim, D.; Fillingane, C.; Pojman, J. A. "Isothermal Frontal Polymerization: Confirmation of the Isothermal Nature of the Process and the Effect of Oxygen and Polymer Seed Molecular Weight on Front Propagation," J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 3601-3608.
  14. Cho, H.; Son, Y. M.; Kim, M. G.; Ra, B. J.; Park, J.-Y.; Lee, S. H.; Choi, J. S.; Song, M. Y.; Park, O. O.; Kim, Y. C.; Hwang, J. T. "Commercial Scale Fabrication Method for Fabricating a
    Gradient Refractive-Index Rod: Overcoming Volume Shrinkage and Chemical Restrictions," Appl. Optics 2006, 45, 7239-7247.

 

Frontal Photopolymerization

(A localized propagation polymerization reaction that is driven by absorption of light.)

 

  1. Koike, Y.; Hatanaka, H.; Otsuka, Y. "Studies on the Light-Focusing Plastic Rod. 17. Plastic Grin Rod Lens Prepared by Photocopolymerization of a Ternary Monomer System," Appl. Opt. 1984, 23, 1779-1783.
  2. Ohtsuka, Y.; Koike, Y. "Studies on the Light Focusing Plastic Rod. 18: Control of Refractive-Index Distribution by Photocopolymerization," Appl. Opt. 1985, 24, 4316-4320.Righetti, P. G.; Bossi, A.; Giglio, M.; Vailati, A.;
  3. Lyubimova, T.; Briskman, V. A. "Is Gravity on our Way? The Case of Polyacrylamide Gel Polymerization," Electrophoresis 1994, 15, 1005-1013.
  4. Briskman, V. A.; Kostarev, K. G. "Polymer Under Microgravity Conditions: Results and Perspectives," Polym. Prepr. (Am Chem. Soc. Div. Polym. Chem.) 2000, 41, 1054-1055.
  5. Briskman, V. A. "Gravitational Effects in Polymerization,"Adv. Space Res. 1999, 24, 1199-1210.
  6. Briskman, V. A.; Kostarev, K. G.; Levtov, V.; Lyubimova, T.; Mashinsky, A.; Nechitailo, G.; Romanov, V. "Polymerization Under Different Gravity Conditions,"Acta Astronautica 1996, 39, 395-402.
  7. Briskman, V. A.; Kostarev, K. G.; Lyubimova, T. P. Gel Polymerization at High Gravity: in Materials Processing in High Gravity; Regel, L. L., Ed.; Plenum: New York, 1994; pp 185-191.
  8. Terrones, G.; Pearlstein, A. J. "Effects of Optical Attenuation and Comsumption of a Photobleaching Initiator on Local Initiation Rates in Photopolymerizations,"Macromolecules 2001, 34, 3195-3204.
  9. Ivanov, V. V.; Decker, C. "Kinetic Study of Photoinitiated Frontal Polymerization,"Polym. Intern. 2001, 50, 113-118.
  10. Miller, G. A.; Gou, L.; Narayanan, V.; Scranton, A. B. "Modeling of Photobleaching for the Photoiniation of Thick Polymerization Systems," J. Poly. Sci.: Part A: Polym. Chem. 2002, 40, 793-808.
  11. Belk, M.; Kostarev, K. G.; Volpert, V.; Yudina, T. M. "Frontal Photopolymerization with Convection,"J. Phys. Chem. B 2003, 107, 10292-10298.
  12. Cabral, J. T.; Hudson, S. D.; Harrison, C.; Douglas, J. F. "Frontal Photopolymerization for Microfluidic Applications,"Langmuir 2004, 20, 10020-10029.
  13. Decker, C.; Keller, L.; Zahouily, K.; Benfarhi, S. "Synthesis of Nanocomposite Polymers by UV-radiation Curing," Polymer, 2005, 46, 6640-6648.
  14. Warren, J. A.; Cabral, J. T.; Douglas, J. F. "Solution of a Field Theory Model of Frontal Photopolymerization.," Phys. Rev. E 2005, 72, 021801.
  15. Tao, Y.; Yang, J.; Zeng, Z.; Cui, Y.; Chen, Y. "Study on Spatial’ÄìTemporal Kinetics of Photo-Initiated Frontal Polymerization in Stacked Reaction Cells," Polym. Intern. 2006, 55, 418-425.
  16. Cui, Y.; Yang, J.; Zeng, Z.; Zeng, Z.; Chen, Y. "Monitoring Frontal Photopolymerization by Electroresistance," Eur. Polym. J. 2007, 43, 3912’Äì3922.
  17. Cui, Y.; Yang, J.; Zeng, Z.; Zeng, Z.; Chen, Y. "Unique Morphology and Properties Study of Polyacrylate Obtained Via Frontal Photopolymerization," Polymer 2007, 48, 5994-6001.
  18. Cui, Y.; Yang, J.; Zhan, Y.; Zeng, Z.; Chen, Y. "In Situ Fabrication of Polyacrylate/Nanozirconia Hybrid Material Via Frontal Photopolymerization," Colloid Polym. Sci. 2008, 286, 97-106.
  19. Kostarev, K. G.; Svistkov, A. L.; Shmyrov, A. V. "Formation of Inhomogeneities in Polyacrylamide Gel in the Course of Frontal Polymerization," Polym. Sci. Ser. A 2008, 50, 710-715.

Other Papers of Interest on Thermal Fronts

Novozhilov, B. V. "The Rate of Propagation of the Front of an Exothermic Reaction in a Condensed Phase,"Dokl. Akad. Nauk SSSR 1961, 141, 151.

 

For Information on Frontal Polymerization Research in the Pojman Lab

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